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Creators/Authors contains: "Chun, Hyun-Myung"

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  1. Abstract We analyze the static response to kinetic perturbations of nonequilibrium steady states that can be modeled as diffusions. We demonstrate that kinetic response is purely a nonequilibirum effect, measuring the degree to which the Fluctuation-Dissipation Theorem is violated out of equilibrium. For driven diffusions in a flat landscape, we further demonstrate that such response is constrained by the strength of the nonequilibrium driving via quantitative inequalities. 
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  2. We study the response of chemical reaction networks driven far from equilibrium to logarithmic perturbations of reaction rates. The response of the mean number of a chemical species is observed to be quantitively limited by number fluctuations and the maximum thermodynamic driving force. We prove these trade-offs for linear chemical reaction networks and a class of nonlinear chemical reaction networks with a single chemical species. Numerical results for several model systems support the conclusion that these trade-offs continue to hold for a broad class of chemical reaction networks, though their precise form appears to sensitively depend on the deficiency of the network. 
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